Berikut adalah hasil matchday pertama Liga Champions Eropa musim 2013/2014 yang berlangsung pada hari Kamis, 19 September 2013:
- Schalke 04 vs Steaua Bucuresti 3-0 (Atsuto Uchida “’67, Kevin Prince Boateng “’78, Julian Draxler “’85)
- Chelsea vs Basel 1-2 (Oscar “’45/ Mohamed Salah “’71, Marco Streller “’81)
- Marseille vs Arsenal 1-2 (Jordan Ayew pen. “’90/ Theo Walcott “’65, Aaron Ramsey “’84)
- Napoli vs Borussia Dortmund 2-1 (Gonzalo Higuain 29″‘, Lorenzo Insigne “’67/ Camilo Zuniga b.d. “’87)
- Austria Wien vs Porto 0-1 (Luis Oscar Gonzalez “’55)
- Atletico Madrid vs Zenit 3-1 (Miranda “’40, Arda Turan “’64, Leo Baptistao “’80 / Hulk “’58)
- AC Milan vs Celtic 2-0 (Emilio Izaguirre b.d. “’82, Sulley Ali Muntari “’86)
- Barcelona vs Ajax 4-0 (Lionel Messi “’22, “’55 dan “’75, Gerard Pique “’69)
